If you've never taken Orgo before, then I strongly recommend you take it within a physical class setting. Orgo is definitely not one of those things you can pass off and learn online - you need to do practice questions like a madman and get as much involvement as you can. I won't say taking the physical lab is necessary (6 hours in a lab setting every week gets tiresome very quickly), but it may help you visualize the reactions in real-time versus just as flow diagrams on paper.
That said, I believe there was only some minimal Orgo II material on the DAT, although I don't know if this has changed since 2013 (when I took my DAT). Most of your focus should be on completing and fully grasping the concepts of Orgo I.
Just my $0.02. You may learn completely differently from me, but I felt that practice questions/reactions were essential to understanding orgo well.
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Organic chemistry I online or self-study for DAT?
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